Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6453346 | Applied Catalysis B: Environmental | 2018 | 9 Pages |
â¢Amorphous NiO co-catalysts are successfully loaded on g-C3N4.â¢The CONi linkages are formed at amorphous NiO/g-C3N4 heterojunctions.â¢Amorphous NiO modified g-C3N4 shows significantly enhanced H2 generation.â¢Amorphous NiO provide more active sites and allow effective light harvesting.â¢Amorphous NiO/g-C3N4 heterojunctions significantly promote the charge separation.
This study was mainly aimed at constructing an amorphous NiO modified g-C3N4 non-noble metal heterojunction photocatalyst for enhanced visible-light hydrogen evolution. The Ni species modified g-C3N4 sample was firstly prepared through the wetness impregnation method and then the phase and crystallinity of Ni species co-catalysts on g-C3N4 were adjusted by the thermal oxidation at different temperature. The detailed characterizations revealed that the amorphous NiO co-catalysts are supported successfully on g-C3N4, and the CONi linkages in the amorphous NiO/g-C3N4 heterojunctions are formed at NiO and g-C3N4 interface after annealing at 300 °C. Compared to bare g-C3N4 and crystalline NiO modified g-C3N4 photocatalysts, amorphous NiO modified g-C3N4 non-noble metal photocatalyst showed significantly enhanced visible-light photocatalytic hydrogen production activity. The amorphous NiO co-catalysts provided more active sites for H2 evolution and amorphous NiO modification caused the enhanced visible-light response. Moreover, amorphous NiO/g-C3N4 heterojunctions formed at interface between amorphous NiO and host g-C3N4 created an inner electric field, which allowed for the transfer of the photogenerated electrons of g-C3N4 across the interfacial CONi linkages to amorphous NiO co-catalysts and thus significantly promoted the migration and separation of photogenerated charge carriers.
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