Research PaperMagnetic Fe2O3/mesoporous black TiO2 hollow sphere heterojunctions with wide-spectrum response and magnetic separation

•Magnetic Fe2O3/mesoporous black TiO2 hollow sphere heterojunctions are fabricated.•It shows wide-spectrum response (∼1800 nm) and magnetic separation.•It exhibits excellent solar-driven photocatalytic degradation performance and long-term stability.•The magnetic separation is conducive to recycle of photocatalyst.•The enhancement is attributed to Ti3+, hollow structure and the formation of heterojunctions.

The solar-light-harvesting and separation of nanostructured photocatalysts in slurry systems are key issues in fields of photocatalysis. Herein, magnetic Fe2O3/mesoporous black TiO2 hollow sphere heterojunctions (M-Fe2O3/b-TiO2) are fabricated through wet-impregnation and surface hydrogenation strategy, which show wide-spectrum response and magnetic separation. The decreased specific surfaces, pore sizes and pore volumes from ∼80 to 67 m2 g−1, ∼12 to 10.3 nm, and ∼0.20 to 0.16 cm3 g−1, respectively, all confirm the efficient loading of magnetic Fe2O3. The M-Fe2O3/b-TiO2 with narrow bandgap of ∼2.41 eV extends the photoresponse from UV to near infrared region and exhibits excellent solar-driven photocatalytic degradation performance and long-term stability for complete mineralization methyl orange and high-toxic herbicide metribuzin. The photocatalytic reaction apparent rate constant k for metribuzin is ∼ 9 times higher than that of pristine TiO2 under AM 1.5 irradiation. Especially for single-wavelength of 950 nm, the degradation ratio is up to 4%. The enhancement is attributed to Ti3+ and magnetic Fe2O3 with narrow bandgap facilitating solar-light-harvesting, the hollow structure benefiting mass transport, and the heterojunctions favoring the spatial separation of photogenerated electron-hole pairs. The magnetic separation is conducive to recycle of photocatalysts, which favors practical applications in environment.

Graphical abstractMagnetic Fe2O3/mesoporous black TiO2 hollow sphere heterojunctions are fabricated through wet-impregnation and surface hydrogenation strategy, which show wide-spectrum response (∼1800 nm) and magnetic separation, and exhibit excellent solar-driven photocatalytic degradation performance and long-term stability due to the synergistic effect of hollow structure, narrowed bandgap and the formation of heterojunctions.Download high-res image (227KB)Download full-size image