Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6454280 | Applied Catalysis B: Environmental | 2017 | 5 Pages |
â¢Ultrathin C3N4 nanosheets serve as efficient cocatalysts for photoelectrochemical water splitting.â¢The H2 generation capability is nearly 12 times with respect to the pristine BiVO4 photoanodes.â¢Ultrathin C3N4 could effectively transfer and store holes for water oxidation.â¢This work may provide an effective approach for enhancing photoelectrochemical properties.
Here, we demonstrate that ultrathin graphitic-phase C3N4 nanosheets (g-C3N4-NS) could serve as an efficient metal-free cocatalyst for improving oxygen evolution activity on nanoporous BiVO4 photoanode. More specifically, as compared with pure BiVO4 photoanode, ultrathin g-C3N4 nanolayers not only suppress the surface charge recombination of BiVO4, but also effectively transfer and store holes for water oxidation. As expected, the ultrathin graphitic-phase C3N4 cocatalyst modified BiVO4 photoanode exhibited significantly improved photocurrent density and H2 generation capability, nearly 7 and 12 times with respect to the pristine BiVO4 under the same conditions. These results demonstrate an effective approach for the design and construction of low-cost and highly efficient PEC systems.
Graphical abstractHere, we demonstrate that ultrathin graphitic-phase C3N4 nanosheets (g-C3N4-NS) could serve as an efficient metal-free cocatalyst for improving oxygen evolution activity on nanoporous BiVO4 photoanode. More specifically, as compared with pure BiVO4 photoanode, ultrathin g-C3N4 nanolayers not only suppress the surface charge recombination of BiVO4, but also effectively transfer and store holes for water oxidation. As expected, the ultrathin graphitic-phase C3N4 cocatalyst modified BiVO4 photoanode exhibited significantly improved photocurrent density and H2 generation capability, nearly 7 and 12 times with respect to the pristine BiVO4 under the same conditions. These results demonstrate an effective approach for the design and construction of low-cost and highly efficient PEC systems.Download high-res image (242KB)Download full-size image