Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6455182 | Catalysis Communications | 2016 | 4 Pages |
Abstract
â¢A novel [(NHC)PdII] unit has been immobilised on silica coated nanoparticles.â¢Good activity shown in Suzuki-Miyaura and chloroarene dehalogenation reactions.â¢Pd-mediated transfer hydrogenation of carbonyl compounds is demonstrated
A novel NHC-palladium(II) (NHCÂ =Â N-heterocyclic carbene) complex and its immobilised version have been prepared and fully characterised. Optimisation studies led to good catalytic activities in Suzuki-Miyaura cross coupling and chloroarene dehalogenation reactions. Furthermore, the unexpected palladium-mediated transfer hydrogenation of a carbonyl compound is reported.
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Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
John-Michael Collinson, James D.E.T. Wilton-Ely, Silvia DÃez-González,