Atomic scale analysis of sterical effects in the adsorption of 4,6-dimethyldibenzothiophene on a CoMoS hydrotreating catalyst

•Atomically resolved scanning tunneling microscopy reveals 4,6-DMDBT adsorption on CoMoS.•The sterically hindered molecule 4,6-DMDBT adsorbs in two configurations on promoted S-edges.•Corner S-vacancies in CoMoS have special affinity for adsorption.•Dynamics between the σ-mode and π-adsorption reveals a link between different HYD and DDS pathways.•Low direct desulfurization activity may be due to low occurrence of S-vacancies on CoMoS edges.

The low catalytic hydrodesulfurization (HDS) activity toward sterically hindered sulfur-containing molecules is a main industrial challenge in order to obtain ultra-low sulfur diesel. In this study we report a combined Scanning Tunneling Microscopy (STM) and Density Functional Theory (DFT) investigation of the adsorption of the sterically hindered sulfur-containing molecule 4,6-dimethyldibenzothiophene (4,6-DMDBT) onto a hydrotreating model catalyst for the Co promoted MoS2 (CoMoS) phase. The molecular adsorption occurs exclusively on the Co-promoted S-edge, most predominantly in a precursor-like diffusive physisorption referred to as delocalized π-mode. 4,6-DMDBT adsorption directly in a S-edge sulfur vacancy is observed exclusively in S-edge corner vacancies in an adsorption configuration reflecting a σ-coordination. STM movies reveal dynamic conversion between the σ-mode and an on-top π-adsorption providing a link between different adsorption sites and hence between the hydrogenation and direct desulfurization pathways in HDS. The low overall direct desulfurization activity of 4,6-DMDBT and related molecules is consistent with the low occurrence of S-vacancies on CoMoS S-edges predicted under HDS conditions in this study.

Graphical abstractDownload high-res image (125KB)Download full-size image