Article ID Journal Published Year Pages File Type
6456402 Journal of Molecular Catalysis A: Chemical 2017 8 Pages PDF
Abstract

•Cage metallasilsesquioxanes as unique structured catalysts.•Calcination of metallasilsesquioxanes as an approach to active inorganic catalysts.•Cage metallasilsesquioxanes in effective functionalization of CH compounds.

The review describes catalytic properties of a unique class of metal complexes-polycyclic cage-like metallasilsesquioxanes. Article is composed in retrospective manner and reflects the progress of the investigations in the field: from classic applications to recently discovered perspectives of cage-like metallasilsesquioxanes in catalysis of oxidation of С-H compounds.

Graphical abstractThe review describes catalytic properties of cage-like metallasilsesquioxanes. The review reflects the progress of the field-from well-known applications of such catalysts to recent discovery of their activity in CH compounds' functionalization.Download high-res image (114KB)Download full-size image

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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