Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6456402 | Journal of Molecular Catalysis A: Chemical | 2017 | 8 Pages |
â¢Cage metallasilsesquioxanes as unique structured catalysts.â¢Calcination of metallasilsesquioxanes as an approach to active inorganic catalysts.â¢Cage metallasilsesquioxanes in effective functionalization of CH compounds.
The review describes catalytic properties of a unique class of metal complexes-polycyclic cage-like metallasilsesquioxanes. Article is composed in retrospective manner and reflects the progress of the investigations in the field: from classic applications to recently discovered perspectives of cage-like metallasilsesquioxanes in catalysis of oxidation of С-H compounds.
Graphical abstractThe review describes catalytic properties of cage-like metallasilsesquioxanes. The review reflects the progress of the field-from well-known applications of such catalysts to recent discovery of their activity in CH compounds' functionalization.Download high-res image (114KB)Download full-size image