MgTi2O5 thin films from single molecular precursor for photoelectrochemical water splitting

•MgTi2O5 films have been produced from [Mg2Ti4(O)2(OH)4(TFA)8(THF)6]·THF complex.•Microspherical designed MgTi2O5 exhibits a photocurrent density of 400 μA/cm2.•MgTi2O5 photoanodes show prolong stability during electrochemical process.

Magnesium dititanate MgTi2O5, thin films have been grown on fluorine doped tin oxide (FTO) substrates using a newly synthesized heterobimetallic single molecular precursor [Mg2Ti4(O)2(OH)4(TFA)8(THF)6]·THF (1) (where TFA=trifluroacetato and THF=tetrahydrofuran) using the aerosol assisted chemical vapor deposition technique (AACVD). The precursor complex (1), isolated in crystalline form by reacting magnesium (II) acetate tertahydrate with titanium (IV) isopropoxide and trifluroacetic acid in THF solution, was characterized by FTIR, single-crystal X-ray diffraction and thermogravimetric analyses. Thin films prepared at 500, 550 and 600 °C were inspected by X-ray diffraction (XRD), field emission gun-scanning electron microscopic (FESEM), and energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS), which demonstrated the development of phase pure orthorhombic porous microspherical objects of MgTi2O5 with precise stoichiometry. The optical analysis showed that MgTi2O5 has a direct band gap of 3.4 eV. The photoelectrochemical (PEC) experiments on MgTi2O5 electrodes showed maximum anodic photocurrent density of 400 μA/cm2 at 0.7 V vs. Ag/AgCl/3 M KCl under simulated solar irradiation of AM 1.5G (100 mW/cm2) in 1 M NaOH. The improved PEC performance of MgTi2O5 electrode was attributed to the increased photo absorption ability, elevated surface area, and more efficient electron/hole transfer which were confirmed by measurements such as linear sweep voltage, transient photocurrent and electrochemical impedance spectroscopy.

Graphical abstractPhotoelectrochemical water splitting have been demonstrated over MgTi2O5 film electrodes, fabricated using single source precursor [Mg2Ti4(O)2(OH)4(TFA)8(THF)6]·THF in aerosol assisted chemical vapor deposition.Figure optionsDownload full-size imageDownload high-quality image (183 K)Download as PowerPoint slide