Article ID Journal Published Year Pages File Type
6470237 Electrochimica Acta 2017 10 Pages PDF
Abstract

•An exact Distribution Function of Relaxation Times (DFRT) has been derived for the fractal Finite Length Warburg (f-FLW).•The DFRT for a true FLW consists of an infinite series of δ-functions.•The impedance of a FLW can be presented by an infinite series of (RC) circuits

An analytic Distribution Function of Relaxation Times (DFRT) is derived for the fractal Finite Length Warburg (f-FLW, also called 'Generalized FLW') with impedance expression: Zf·FLW(ω) = Z0 · tanh(ωτ0)n · (ωτ0)−n. τ0 is the characteristic time constant of the f-FLW. Analysis shows that for n → 0.5 (i.e. the ideal FLW) the DFRT transforms into an infinite series of δ-functions that appear in the τ-domain at positions given by τk = τ0/[π2(k − ½)2] with k = 1, 2, 3, … ∞. The mathematical surface areas of these δ-functions are proportional to τk. It is found that the FLW impedance can be simulated by an infinite series combination of parallel (RkC0)-circuits, with Rk = C0×τk−1 and τk as defined above. Rk = 2τk×Z0 and C0 = 0.5×Z0−1. Z0 is the dc-resistance value of the FLW.A full analysis of these DFRT expressions is presented and compared with impedance inversion techniques based on Tikhonov regularization and multi-(RQ) CNLS-fits (m(RQ)fit). Transformation of simple m(RQ)fits provide a reasonably close presentation in τ-space of the f-FLW, clearly showing the first two major peaks. Impedance reconstructions from both the Tikhonov and m(RQ)fit derived DFRT's show a close match to the original data.

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