| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6470508 | Electrochimica Acta | 2017 | 7 Pages |
â¢Toluene-methylcyclohexane organic hydride system performed by electrocatalytic process.â¢Porous-carbon flow-field showed the highest current efficiency.â¢Porous-carbon indicated a suppression effect for generation of side hydrogen-gas reaction.â¢Porous structure as flow-field enhanced the toluene mass transfer to catalyst layer.
In this study, we investigated the effect of the design of the cathode flow-field structure on the electrochemical performance of the electrolyzer for the toluene-methylcyclohexane electrocatalytic hydrogenation synthesis system. The patterns of the basic flow-fields; i.e. parallel, interdigit, serpentine and porous-carbon, were investigated based on linear sweep voltammetry (LSV), internal, and cathodic and anodic charge transfer resistances with impedance spectroscopy and current efficiency. The flow-field pattern affected the toluene mass transportation and H2 gas generation as a side reaction. Based on the LSV curve, the porous-carbon did not affect the overvoltage for the decrease in the toluene concentration, and showed the lowest cell voltage in the all flow-fields. The cathodic charge transfer resistance by impedance analysis and the current efficiency of the porous-carbon showed the highest performance in the all flow-fields over a wide toluene concentration range.
Graphical abstractCurrent efficiency of electrocatalytic-hydrogenation for toluene-methylcyclohexane organic hydride system significantly increased with optimization of cathode flow field structure. Porous-carbon cathode flow-field maintained the highest property for all region of toluene concentration.Download high-res image (125KB)Download full-size image
