Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6470689 | Electrochimica Acta | 2017 | 10 Pages |
â¢The binary PdAu nanoflowers supported by N-doped graphene are fabricated.â¢The morphology of PdAu/NG is PVP-dependent.â¢The ultrasonic procedure is crucial for the synthesis of desirable PdAu/NG.â¢The obtained PdAu/NG exhibit outstandingly high electrocatalytic performances.
The design of cost-efficient catalysts for the electrooxidation of small organic molecules are highly desirable for the commercial application of direct fuel cells. Shape-controlled PdAu alloys with N-doped graphene support are highly efficient electrocatalysts for the electrooxidation of ethylene glycol and glycerol in the alkaline media. Impressively, the newly generated Pd1Au1-NF/NG catalysts prepared by a facile ultrasonic-assisted synthetic method in this work exhibit the unprecedentedly high mass activities with 12.8 and 8.7Â AÂ mg â1 towards ethylene glycol and glycerol oxidation, which are 10.07- and 12.25-fold enhancements than that of commercial Pd/C catalyst (1.27 and 0.71Â AÂ mg â1), respectively. This work may open a new way in enlarging the surface area and ultimately maximizing the electrocatalytic activities by tuning the morphology of metallic alloy and introducing the appropriate catalyst supports.
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