Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6471245 | Electrochimica Acta | 2017 | 7 Pages |
Carbon materials have been widely applied in the energy storage devices, however, the preparation of suitable carbon materials for sodium-ion batteries (SIBs) is still a challenge. In this paper, N-doped porous carbon material (NDPCs) with rose-like structure has been successfully prapared through pyrolysis of the as-prepared polyimides in-situ. The NDPCs shows rose-like structure derived from 2D nanosheets, an expanded interlayer distance of 0.387 nm, a high specific surface area of 215.7 m2 gâ1 and the electrochemical performances for Na-ion batteries are systematically investigated. A high reversible specific capacity of 240 mAh gâ1 at a current density of 100 mA gâ1 is attained and a specific capacity of 224 mAh gâ1 is remained even after 100 cycles. Remarkably, even at a high current density of 3.2 A gâ1, the reversible specific capacity of 104 mAh gâ1 can be observed. This excellent performance of NDPCs electrode may be ascribed to its superior structure, since the micropore/mesopore might efficiently shorten the diffusion distance of Na-ion and the enlarged interlayer spacing of 0.38 nm is significant for Na-ion insertion/extraction. Significantly, the approach to prepare carbon materials from PI may be generalized to other polymers.