Article ID Journal Published Year Pages File Type
6471931 Electrochimica Acta 2017 10 Pages PDF
Abstract

•Synthesis of the new ionic liquid, Pyr14TDI.•Thermal and electrochemical properties of Pyr14TDI-LiTDI.•Pyr14TDI-LiTDI mixture as electrolyte for lithium battery application.•Performance of Li/Pyr14TDI-LiTDI/LiFePO4 cells.

A new ionic liquid formed by coupling 4,5-dicyano-2-(trifluoromethyl)imidazole (TDI−) anion with N-butyl -N-methyl-pyrrolidinium (Pyr14+) cation is successfully synthesized and characterized by Raman spectroscopy, thermal and rheological analyses, as well as electrochemical techniques. The Pyr14TDI-LiTDI mixture, melting at 49 °C, shows remarkable stability within the 50-250 °C range, as well as suitable ionic conductivity, lithium ion transport, and electrochemical stability window. Thus, it is proposed for application at 60 °C in a lithium cell with stable LiFePO4 cathode. At this temperature, the electrolyte has viscosity of 65.8 mPa s, ionic conductivity of the order of 5 mS cm−1, and limiting current density of 10−2 mA cm−2. Lithium metal/LiFePO4 cells with such an electrolyte offer promising results in terms of stable LiFePO4/electrolyte interface, investigated by impedance spectroscopy, as well as delivered capacity above 160 mAh g−1 with 81% of retention after 80 galvanostatic cycles.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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