Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6471954 | Electrochimica Acta | 2017 | 26 Pages |
Abstract
A compact TiO2 (c-TiO2) layer fabricated by spin coating or spray pyrolysis following a high-temperature sintering is a routine in high-performance planar heterojunction perovskite solar cells. Here, we demonstrate an effective low-temperature approach to fabricate an ultrathin and discrete TiO2 (u-TiO2) for enhancing photovoltaic performance of perovskite solar cells. Via hydrolysis of low-concentration TiCl4 solution at 70 °C, u-TiO2 was grown on a fluorine doped tin oxide (FTO) substrate, forming the electron selective contact with the photoactive CH3NH3PbI3 film. The perovskite solar cell using u-TiO2 achieves an efficiency of 13.42%, which is compared to 13.56% of the device using c-TiO2 prepared by high-temperature sintering. Cyclic voltammetry, steady-state photoluminescence spectroscopy and electrical impedance spectroscopy were conducted to study interface engineering and charge carrier dynamics. Our results suggest that u-TiO2 functions as a bridge for electron transport between perovskite and FTO, which accelerates electron transfer and alleviates charge recombination.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Xiaokun Huang, Ziyang Hu, Jie Xu, Peng Wang, Jing Zhang, Yuejin Zhu,