| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 64761 | Journal of Molecular Catalysis A: Chemical | 2016 | 7 Pages |
•Homogeneous catalytic isomerization of allylic-alcohols in presence of water.•Ru complexes containing the open adamantane phosphine dmoPTA.•Bi-heterometallic-Ru–M complexes (M = Co, Ni, Zn) containing dmoPTA.•Water and pH influence on the catalytic isomerization of allylic-alcohols.
The catalytic activity of [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (1) and the dimeric complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N'-MCl2] (M = Ni (2), Co (3), Zn (4)) for the isomerization in water under Ar and ambient atmosphere of 1-octen-3-ol, 1-hepten-3-ol and 1-hexen-3-ol was investigated. A detailed study was devoted to the catalytic activity under Ar of 1 for the isomerization of 1-octen-3-ol.
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 in the isomerization of allylic alcohols in water (dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)](/preview/png/64761.png "First Page Preview: Evaluation of catalytic activity of [RuClCp(dmoPTA)(PPh3)](OSO2CF3) in the isomerization of allylic alcohols in water (dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)")