| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6497869 | Applied Catalysis A: General | 2011 | 12 Pages |
Abstract
ⶠNitrogen-substituted NaY shows much increased base strength compared to NaY. ⶠNit-NaY is highly active for liquid phase aldol condensation reactions of furfural/HMF with acetone/propanal, comparable to a strong solid base MgO-ZrO2. ⶠNit-NaY shows shape selectivity towards aldol monomer product due to the FAU-typed crystal structure. ⶠNit-NaY is unstable due to the leaching of framework nitrogen under current operation conditions, while MgO-ZrO2 shows good recyclability.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Wenqin Shen, Geoffrey A. Tompsett, Karl D. Hammond, Rong Xing, Fulya Dogan, Clare P. Grey, W. Curtis Jr., Scott M. Auerbach, George W. Huber,