Article ID Journal Published Year Pages File Type
6500561 Applied Catalysis B: Environmental 2015 35 Pages PDF
Abstract

- Propylamine (PA) hydroconversion was applied as model reaction of bone oil HDN.
- The Ni2P/SiO2 catalyst was active in the C-N but inactive in C-C hydrogenolysis.
- Operando DRIFTS study confirmed that DPA is intermediate of the PA HDN reaction.
- The protonated N-bases over the Ni2P/SiO2 catalyst are spectator species in the reaction.
- Defective Ni2P crystals of fresh catalysts take up ordered structure during reaction.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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