| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6502032 | Applied Catalysis B: Environmental | 2013 | 8 Pages |
Abstract
- Alkaline metals Li, K, Rb and Cs were efficient for tune acidity of H4SiW12O40.
- Li modified Pt-H4SiW12O40/ZrO2 exhibited superior 1,3-propanediol selectivity.
- 1,3-Propanediol yield was proportional to the concentration of Brønsted acid sites.
- A mechanistic scheme for glycerol hydrogenolysis to 1,3-propanediol was proposed.
- A 120Â h long-term performance for Pt-H4SiW12O40/ZrO2 was achieved.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Shanhui Zhu, Xiaoqing Gao, Yulei Zhu, Yifeng Zhu, Xiaomin Xiang, Caixia Hu, Yongwang Li,