Article ID Journal Published Year Pages File Type
6502078 Applied Catalysis B: Environmental 2013 11 Pages PDF
Abstract

- Isocyanate formation and reactivity was studied on a model LNT catalyst.
- According to DRIFTS data, Ba-NCO is derived from the reduction of Ba(NO3)2 by CO.
- Subsequent reaction of isocyanate with residual nitrates is slow.
- During dry lean-rich cycling, N2 mainly formed via the reaction of NCO with NO/O2.
- H2O is the most reactive species toward isocyanate of those tested.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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