Article ID Journal Published Year Pages File Type
6502333 Applied Catalysis B: Environmental 2013 11 Pages PDF
Abstract
► Ni/Al2O3-HZSM-5 had almost three times more accessible Ni atoms than Ni/HZSM-5. ► TPR found that Ni oxide on Al2O3-HZSM-5 was more difficult to reduce due to the formation of NiO-Al2O3 'pseudo spinels'. ► The BAS concentration of Ni/Al2O3-HZSM-5 highly decreased because the small Ni nanoparticles nucleated at obstructed BAS sites. ► The in situ IR showed that Al2O3-HZSM-5 had higher adsorption capacities than HZSM-5 due to the added γ-Al2O3 binder.
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Physical Sciences and Engineering Chemical Engineering Catalysis
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