Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6502689 | Applied Catalysis B: Environmental | 2011 | 8 Pages |
Abstract
ⶠpH plays a significant role in both photolysis and heterogeneous photocatalysis of the emerging contaminants ciprofloxacin and moxifloxacin in water. ⶠThe third generation fluoroquinolone moxifloxacin is more susceptible to photocatalytic degradation than the second generation fluoroquinolone ciprofloxacin. ⶠFirst-order degradation rate constants and partition ratios of the different fluoroquinolone species reveal that the photocatalytic degradation rate is strongly determined by the pH dependent adsorption on the TiO2 catalyst surface.
Keywords
Orthogonal distance regressionODRAOPPDADDDESACPZCCIPISCROSvdWPhotodiode array detectorconduction bandMOXAdsorptionDefined daily doseCiprofloxacinPhotolysisAdvanced oxidation processFluoroquinoloneHeterogeneous photocatalysisResidual sum of squaresMoxifloxacinpoint of zero chargeVan der WaalsHigh pressure liquid chromatographyHPLCvalence bandReactive oxygen species
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Xander Van Doorslaer, Kristof Demeestere, Philippe M. Heynderickx, Herman Van Langenhove, Jo Dewulf,