| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6502939 | Catalysis Communications | 2018 | 5 Pages |
Abstract
The lanthanide aryloxides Ln(OAr)3(THF)2 (Arâ¯=â¯Ar1â¯=â¯2,6-tBu2-4-MeC6H2, Lnâ¯=â¯Yb (1), Y (2); Arâ¯=â¯Ar2â¯=â¯2,6-iPr2C6H3, Lnâ¯=â¯Y (3); Arâ¯=â¯Ar3â¯=â¯2,6-Me2C6H3, Lnâ¯=â¯Y (4); Arâ¯=â¯Ar1, Lnâ¯=â¯Sm (5), Nd (6)) could be served as highly efficient catalysts for the hydroboration of aldehydes and ketones with good functional group tolerance and excellent chemoselectivity. Computational studies were carried out to probe a feasible mechanism of the Ln-aryloxides catalyzed hydroboration of aldehydes/ketones.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Zhangye Zhu, Ping Dai, Zhenjie Wu, Mingqiang Xue, Yingming Yao, Qi Shen, Xiaoguang Bao,