| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6503768 | Catalysis Communications | 2012 | 5 Pages |
Abstract
⺠Combination Mn complex/oxalic acid catalyzes epoxidation of methyl oleate with H2O2. ⺠The reaction proceeds under very mild conditions (25 ºC). ⺠Yield and selectivity attained 100%, turnover numbers were up to 2000. ⺠The oxidation proceeds with the participation of high-valent oxo-manganese species.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
![Oxidations by the system 'hydrogen peroxide-[Mn2L2O3]2Â + (LÂ =Â 1,4,7-trimethyl-1,4,7-triazacyclononane)-carboxylic acid'](/preview/png/6503768.png "First Page Preview: Oxidations by the system 'hydrogen peroxide-[Mn2L2O3]2Â + (LÂ =Â 1,4,7-trimethyl-1,4,7-triazacyclononane)-carboxylic acid'")
Authors
Dalmo Mandelli, Yuriy N. Kozlov, Wagner A. Carvalho, Georgiy B. Shul'pin,