Article ID Journal Published Year Pages File Type
6505094 Catalysis Today 2016 8 Pages PDF
Abstract

- WO3/C and Ru/C catalyze cellulose conversion to polyols including sorbitol, propylene glycol and ethylene glycol.
- Crystalline WO3 catalyzes selective cleavage of C-C bonds in sugar intermediates involved in cellulose reaction.
- C support acts as a solid base to catalyze glucose isomerization into fructose.
- Polyol product distribution is controllable rationally by tuning the catalyst functions for the competitive reactions of glucose intermediate.
- Kinetic analysis of the competitive glucose reactions can predict the maximum yield of propylene glycol in cellulose reaction.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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