| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6505519 | Catalysis Today | 2013 | 8 Pages |
Abstract
⺠Catalysts prepared by supporting (NH4)3HPMo11VO40 (APMV) on various silica carriers and on Cs3PMo12O40 (CPM). ⺠Catalytic performance for the selective oxidation of isobutane to methacrolein and methacrylic acid was evaluated. ⺠The highest yield (8%) was obtained with CPM-supported APMV at 15.3 mol.% isobutane conversion. ⺠The support exerts a strong effect on the dispersion and on the thermal stability and on acidity of APMV. ⺠Silica-supported catalysts were poorly stable as compared with CPM-supported. ⺠Decomposition of APMV was delayed by supporting it on CPM, and preserved the strongest acid sites necessary in the reaction.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Fangli Jing, Benjamin Katryniok, Elisabeth Bordes-Richard, Sébastien Paul,