| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6505562 | Catalysis Today | 2013 | 5 Pages |
Abstract
⺠The catalytic activity of 2 wt% Ir/TiO2 in alcohol oxidation with molecular oxygen was enhanced by high-temperature hydrogen reduction. ⺠Kinetic analysis revealed that adsorption of alcohol was enhanced by high-temperature hydrogen reduction. ⺠Formation of partially reduced titanium oxide by high-temperature hydrogen reduction is well known phenomenon as the SMSI effect. ⺠Coordinatively unsaturated titanium sites formed by the SMSI effect may work as coordination sites of alcohols to enhance catalytic activity.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Akihiro Yoshida, Yoshinori Mori, Tsuyoshi Ikeda, Kazuki Azemoto, Shuichi Naito,