Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6505574 | Catalysis Today | 2013 | 6 Pages |
Abstract
⺠Gold- and base catalysed formation of amides by oxidative coupling of alcohols and amines in methanol. ⺠Hammett study provides mechanistic insight by determination of the relative reactivity. ⺠DFT calculations on possible mechanisms of the aminolysis of the intermediate methyl ester product allow correlation between theoretical and experimentally Hammett plots.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Jerrik Mielby, Anders Riisager, Peter Fristrup, Søren Kegnæs,