Heterogenization of ionic liquid based on mesoporous material as magnetically recyclable catalyst for biodiesel production

•The catalyst possessed magnetic core and ionic liquid modified mesoporous shell.•A desirable loading of ionic liquid was achieved due to the large surface area.•A high biodiesel yield of 93.5% was obtained under mind conditions.•The catalyst allowed for a rapid separation in magnetic field.

To develop green and reusable catalysts for the biodiesel preparation, a novel magnetically separable nanocatalyst was fabricated by covalent bonding of 3-sulfopropyl-1-(3-propyltrimethoxysilane) imidazolium hydrogen sulfate ([SO3H-PIM-TMSP]HSO4) on mesoporous silica modified Fe3O4 nanoparticle. The catalyst possessed uniform core-shell structure with magnetic response core and Brønsted ionic liquid functionalized mesoporous silica shell. The multifunctional catalyst also exhibited appealing physicochemical features like high specific surface area, mesoporous channel, magnetic response, and fine catalytic activity in esterification of oleic acid with alcohol. Under mind conditions, the conversion of oleic acid was up to 93.5%. The catalyst exhibited recyclable property based on magnetism and the separation of the catalyst would be simply using external magnetic field without obvious mass loss, allowing a clean biodiesel product.

Graphical abstractThe combination of nano-Fe3O4, mesoporous silica and acidic ionic liquid made an efficient and recyclable catalyst for the biodiesel production.Figure optionsDownload full-size imageDownload high-quality image (177 K)Download as PowerPoint slide