| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6527574 | Journal of Catalysis | 2014 | 7 Pages |
Abstract
- Kinetic data and DFT used to study C-C rupture on Ir clusters.
- C2-intermediates formed by quasi-equilibrated adsorption and dehydrogenation.
- Close agreement between measured kinetic barrier and DFT-derived barriers.
- C-C cleavage occurs via *CHCH*Â >Â 107 times faster than for other intermediates.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
David W. Flaherty, David D. Hibbitts, Elif I. Gürbüz, Enrique Iglesia,