Article ID Journal Published Year Pages File Type
6527705 Journal of Catalysis 2013 5 Pages PDF
Abstract
The hydride transfer between isobutane isotopomers in acidic zeolite has been studied by in situ NMR. The activation energy and the kinetics of the reaction have been determined. The experimental observations support a carbenium based mechanism.
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Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
Preview
Activation energy of hydride transfer between isobutane molecules on USY zeolite. First direct experimental measurement by in situ MAS NMR using mixtures of isotopomers
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