| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6527828 | Journal of Catalysis | 2013 | 9 Pages |
Abstract
⺠Elementary reaction steps of SMR for Pt(111), Pt(533) and Pt(210) calculated by DFT. ⺠The rate-controlling step is dissociative methane adsorption. ⺠Rhodium is more active than platinum in methane steam reforming. ⺠The reaction mechanism toward CO depends on metal and surface topology. âºAn alcoholate intermediate is implicated for Pt(210) in contrast to Rh(211).
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Tianwei Zhu, Pieter W. van Grootel, Ivo A.W. Filot, Shi-Gang Sun, Rutger A. van Santen, Emiel J.M. Hensen,