| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6527861 | Journal of Catalysis | 2012 | 14 Pages |
Abstract
⺠Mechanism of the Pt-catalyzed hydrosilylation of allyl compounds. ⺠Byproducts are formed via different reaction pathways. ⺠Oxidative addition and insertion into the Pt-H bond represent the crucial, selectivity-determining steps. ⺠DFT calculations support the experimental results.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Peter Gigler, Markus Drees, Korbinian Riener, Bettina Bechlars, Wolfgang A. Herrmann, Fritz E. Kühn,