Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6527883 | Journal of Catalysis | 2012 | 11 Pages |
Abstract
⺠Regioselectivity of the initial protonation of sugars determines selectivity of their conversion. ⺠Favorable protonation of fructose opens path to levulinic acid via HMF intermediate. ⺠Favorable protonation of glucose leads to reversion products and humin precursors. ⺠Novel direct mechanism of glucose transformation to levulinic acid is reported.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Gang Yang, Evgeny A. Pidko, Emiel J.M. Hensen,