| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6527921 | Journal of Catalysis | 2012 | 10 Pages |
Abstract
⺠Fluoride-treated H-ZSM-5 is highly selective for C3H6 formation from CH3Cl or CH3Br. ⺠Fluoride treatment decreases acidity, inhibiting secondary reactions of light olefins. ⺠Fluoride treatment generates larger micropores in ZSM-5, increasing C3H6 selectivity. ⺠Conversion of methyl halide to light olefins proceeds via hydrocarbon pool mechanism. ⺠Acidity and porous structure determine the catalytic conversion of methyl halides.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Ting Xu, Qinghong Zhang, Hang Song, Ye Wang,