Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6527922 | Journal of Catalysis | 2012 | 12 Pages |
Abstract
⺠Calcined Al, Ga, In and ZrO nitrates showed strong Brønsted and Lewis acidity. ⺠Calcined zirconyl nitrate led to the best catalytic results (98%Sel at 57%Conv.). ⺠High strength Brønsted plus Lewis acidity correlates with crotyl alcohol yield. ⺠Catalysts presented a severe deactivation process (both reversible and irreversible). ⺠Adsorbed polymeric species on strong acid sites relate to irreversible deactivation.
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Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Juan F. Miñambres, Alberto Marinas, José M. Marinas, Francisco J. Urbano,