| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6527992 | Journal of Catalysis | 2012 | 7 Pages |
Abstract
⺠Kinetic orders with respect to H2 and CO are dependent upon reaction temperature. ⺠Reaction temperature is a tunable parameter to control the regioselectivity. ⺠The rate-determining step is alkene insertion and oxidative addition of H2 at low and high temperature, respectively. ⺠Derived rate expressions are consistent with kinetic studies and can be used to adequately model the experimental data.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
David G. Hanna, Sankaranarayanapilla Shylesh, Sebastian Werner, Alexis T. Bell,