| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6528159 | Journal of Catalysis | 2012 | 7 Pages |
Abstract
⺠Metal chlorides of easily changeable valence are active to cyclohexane photo-oxidation. ⺠Metal chlorides absorb visible light due to its weak coordination with solvent. ⺠Acetone is slightly superior to acetonitrile in the improved oxidative selectivity. ⺠Adding concentrated HCl can significantly promote the CuCl2-photocatalyzed cycling. ⺠A mechanism of light-driven redox cycling of CuCl2 for the photoreaction is proposed.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Wenfeng Wu, Xiangling He, Zaihui Fu, Yachun Liu, Yanlong Wang, Xinglang Gong, Xiaolin Deng, Haitao Wu, Yanhong Zou, Ningya Yu, Dulin Yin,