Article ID Journal Published Year Pages File Type
6528304 Journal of Catalysis 2012 11 Pages PDF
Abstract
► CeO2 is a cost-effective alternative to RuO2 for catalyzed Cl2 production. ► HCl oxidation activity of CeO2 is linked to oxygen vacancies. ► Calcination temperature key to maximize activity and structural stability. ► The chlorination extent of CeO2 depends on the feed O2/HCl ratio and is highly dynamics. ► Catalyst re-oxidation is rate-determining step.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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