| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6530773 | Journal of Molecular Catalysis A: Chemical | 2013 | 12 Pages |
Abstract
- Rhn + N2O reaction study must consider the geometry of the reactants and spin.
- N2O reduction mechanism catalysed by Rhn clusters ends up breaking the N2O bond.
- The N2O activation never occurs through the NN bond rupture.
- Most of Rh clusters capture N2O and there are some spin states that also activate it.
- The spin states transfer enough charge from Rh to N2O to break the N2O bond.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
R. Avilés, E. Poulain, O. Olvera-Neria, V. Bertin,