| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6530820 | Journal of Molecular Catalysis A: Chemical | 2011 | 7 Pages |
Abstract
ⶠAn ammonium tagged carbapalladacycle has been synthesized in good overall yield and is well characterized. ⶠAn organic-inorganic hybrid system has been synthesized by intercalating the synthesized carbapalladacycle in between the layers of Na+-MMT clay. ⶠThe ammonium tag facilitates the intercalation of carbapalladacycle by increasing organophilicity of clay. ⶠThe prepared carbapalladacycle and its clay-nanocomposite have been efficiently used as recyclable catalytic system in ionic liquid media for carrying out Mizoroki-Heck and Sonogashira reactions with high TONs/TOFs. ⶠThe catalytically inert ammonium tag does not interfere in the reaction, instead being ionophilic it enhances the immobilization of carbapalladacycle in ionic liquid medium.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
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Authors
Vasundhara Singh, Rajni Ratti, Sukhbir Kaur,