Simultaneously application of SBA-15 sulfonic acid nanoreactor and ultrasonic irradiation as a very useful novel combined catalytic system: An ultra-fast, selective, reusable and waste-free green approach

•Simultaneously application of SBA-15 sulfonic acid nanoreactor and ultrasonic irradiation as a combined catalytic system.•An efficient and green approach for synthesis of indazolophthalazinetrione, polyhydroquinoline and aminophosphonates.•Represents advantages, operational simplicity, higher and yield with ultrasonic irradiation and then filterable workup.

Sonicated catalytically amount of the SBA-15/SO3H nanoreactor with organic substrate was found to be an efficient, ultra-fast and waste-free green approach for the synthesis of the indazolophthalazinetriones, polyhydroquinolines and α-aminophosphonates as models of organic reactions. The advantages of present combined method are the use of a low scale catalyst, simple procedure with an easy filterable work-up method, waste-free, green and direct synthetic entry to excellent yield of products in a high reusability and a short reaction time. SBA-15 nanoreactor anchored covalently bonded PrSO3H organic groups, to produce organic–inorganic mesochannels, in reaction condition (combined ultrasound/nanoreactor system) as catalyst provide a synergistic means of an efficient approach of the reactants to acidic sites, and suitable mesochannels to drive out the products and water for next recycles.

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