Application of silica vanadic acid as a heterogeneous, selective and highly reusable catalyst for oxidation of sulfides at room temperature

Silica vanadic acid (vanadium has been supported on silica) is applied as an efficient, highly reusable and heterogeneous catalyst for the selective oxidation of sulfide to sulfoxide using hydrogen peroxide and in the acetonitrile as a solvent at room temperature. The catalyst can be easily recovered and reused for ten reaction cycles without considerable loss of activity. Also, some advantages of this method were applicable at large scales, high TON of catalyst, chemoselectivity, easy work-up and short reaction time.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (106 K)Download as PowerPoint slideHighlights► Application of supported transition metal oxides catalyst. ► Using catalyst in large scale. ► High reusable catalyst. ► Chemoselectivity and homoselectivity. ► High TON and TOF.