| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 65925 | Journal of Molecular Catalysis A: Chemical | 2013 | 8 Pages |
A series of vanadium(V) complexes with chiral tridentate Schiff base ligands, obtained by a single condensation of R(−)-1-amino-2-propanol with salicylaldehyde and its derivatives, were prepared. The complexes were characterized by elemental analysis and by their IR, CD, UV–Vis, 1D (1H, 51V) and 2D (COSY, gHSQC) NMR spectra. The vanadium(V) complexes have ability to catalyze the oxidation of sulfides [PhSR (R = Me, Bz)] in good yields and enantiomeric excesses, utilizing aqueous 30% H2O2 or cumene hydroperoxide (CHP) as oxidant. Catalytic activity of these complexes and also derived from R(−)-1,2-diaminopropane, resulted in ONO- and ONN-type of tridentate ligands, respectively, were tested in the oxidation of styrene, using aqueous 30% H2O2 or tert-butyl hydroperoxide (TBHP) as oxidant.
Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (64 K)Download as PowerPoint slideHighlights► Vanadium(V) Schiff base complexes derived from chiral amino alcohol were synthesized. ► The vanadium(V) complexes have ability to catalyze the oxidation of sulfides. ► The yields and enantiomeric excesses significantly depend on the nature of the catalyst, substrate and peroxide used. ► The vanadium(V) complexes are also catalytically active in the oxidation of styrene.
