Scaling of the detonation product state with reactant kinetic energy

Chemical explosives provide one of the most high-power and energy-dense storage materials available. During detonation, transfer of this energy to adjacent materials is governed by the detonation product equation of state. No accurate methodology exists for prediction of this thermodynamic relationship and equation-of-state data continues to be experimentally characterized for each new formulation or charge density. Here we present a universal detonation product equation of state derived from several newly discovered empirical correlations in prior condensed-phase detonation product measurements. This model depends only on initial charge density and detonation velocity as inputs, dramatically simplifying the calibration process relative to existing models, which require measurement of up to seven formulation-specific parameters. This new result implies the product energy density scales with reactant kinetic energy density, which is the product of the explosive initial density and detonation velocity squared, for all condensed-phase energetic materials and that explosive microstructural or chemical details only influence the product energy density though these two parameters.