Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6594604 | Comptes Rendus Chimie | 2010 | 9 Pages |
Abstract
Me3SiCP may be prepared by dehydrochlorination of Me3SiCH2PCl2 at room temperature in aromatic solvents using DABCO in the presence of AgOTf. Reaction of Me3SiCP with a selection of s-block metals, s-block metal salts and ytterbium effects conversion to a mixture of di- and triphospholide anions. This mixture of anions was subsequently reacted with FeCl2 to yield a mixture of tetra-, penta- and hexaphosphaferrocenes.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Stephen M. Mansell, Michael Green, Richard J. Kilby, Martin Murray, Christopher A. Russell,