Scheduling of cracking production process with feedstocks and energy constraints

This paper addresses the short-term scheduling problem for the ethylene cracking process with feedstocks and energy constraints. The cracking production of ethylene is a process with units that have decaying performance, requiring periodic cleanup to restore their performance. Under the condition of limited feedstocks, the production operating mode of the cracking furnaces is to keep yields constant by continuously increasing the coil temperature. We present a hybrid MINLP/GDP formulation based on continuous-time representation for the scheduling problem over a finite time horizon. In order to solve the proposed model, which is reformulated as an MINLP model, an improved outer approximation algorithm with multi-generation cuts and problem-dependent integer cuts are developed to solve real large-scale problems. Numerical examples are presented to illustrate the application of the model. Based on analyzing the optimal solution and sensitivity of the model, some conclusions are obtained to provide useful suggestions for real cracking process production.