Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6602818 | Electrochimica Acta | 2018 | 31 Pages |
Abstract
Ionic liquid (IL) electrolytes have been applied to lithium ion capacitors (LICs) composed of porous three-dimensional (3D) current collector. LIC cells containing IL electrolytes showed reversible charge-discharge potential profiles and their capacity degradation was hardly observed during 3000 cycles. In particular, a cell with 1-ethyl-3-methyl imidazolium bis(fluorosulfonyl)imide (EMImFSI) containing lithium FSI (LiFSI) as Li salt kept over 90% of its initial capacity even after 3000 cycles. The EMImFSI-based IL electrolyte system (LiFSI/EMImFSI) also provided better rate performance than that of a conventional LiPF6-based organic electrolyte system. Considering high-temperature (60â¯Â°C) characteristics in the IL system and LiPF6-based system, charge-discharge operation in LiFSI/EMImFSI was stable compared to that in the LiPF6-based solvent system. Moreover, the LIC cell with LiFSI/EMImFSI was stably cycled even at 0â¯Â°C and its discharge capacity was superior to that of the LiPF6-based solvent electrolyte at 0â¯Â°C.
Related Topics
Physical Sciences and Engineering
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Authors
Naoya Hirota, Kazuki Okuno, Masatoshi Majima, Akihisa Hosoe, Satoshi Uchida, Masashi Ishikawa,