Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6603128 | Electrochimica Acta | 2018 | 11 Pages |
Abstract
3D-ordered porous nitrogen and sulfur co-doped carbon (NS/C) is synthesized from the functionalized fluidic acrylonitrile telomer (ANT) as C, N and S source. The dispersed PdCuW nanoparticles with an average size of 5.25â¯nm are supported on the walls of the NS/C by a glycol reduction method. Compared with 20%Pd black (Pd/C), NS/C and 20%Pd-NS/C, it is found that PdCuW-NS/C composite with 11.4â¯wt% Pd exhibits superior catalytic activity for oxygen reduction reaction (ORR) in alkaline solution. Moreover, PdCuW-NS/C possesses higher capacities, lower overpotentials and better cyclic stability as cathode materials for Li-O2 batteries; the cyclic retention of more than 70 cycles are achieved at 300â¯mAâ¯gâ1 with the restricted capacity at 500â¯mAh gâ1.
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Authors
Sen Lin, Yongliang Li, Shan Luo, Xiangzhong Ren, Libo Deng, Hongwei Mi, Peixin Zhang, Lingna Sun, Yuan Gao,