Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6605056 | Electrochimica Acta | 2017 | 7 Pages |
Abstract
The cycling performances of pristine and modified materials are investigated by galvanostatic cycles at several charge/discharge rates. A detailed analysis of the interfacial properties, and of their impact toward cycling behavior, is carried out by combining galvanostatic cycles at 1C and electrochemical impedance spectroscopy at T = 25 °C and T = 50 °C. The results show that the electrode/electrolyte interface of Al2O3-modified LiMn2O4 is stabilized by suppressing Mn dissolution, resulting in improved cycleability, especially at high temperatures. These results are corroborated by X-ray photoelectron spectroscopy studies, which confirm the suppression of Mn dissolution for the Al2O3-coated material.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
M. Pasqualini, S. Calcaterra, F. Maroni, S.J. Rezvani, A. Di Cicco, S. Alexander, H. Rajantie, R. Tossici, F. Nobili,