Article ID Journal Published Year Pages File Type
6606187 Electrochimica Acta 2016 33 Pages PDF
Abstract
Herein, the algae pollutants of Enteromorpha prolifera were applied as precursors to obtain nitrogen and oxygen co-doped hierarchical carbons with major pores at around 1.5 and 5.0 nm through direct carbonization at 700 and 900 °C after freeze-drying treatment. Physical properties of porous carbons including morphology, elemental analysis, and pore size distribution were evaluate by transmission electron microscopy, X-ray photoelectron spectroscopy and N2 sorption. In both cases, surface areas were only close to 450 m2 g−1 with 70% areas inherited from mesopores, resulting in high density materials. The carbon derived at 700 °C had the highest capacitance of 234 F g−1 at a current density of 0.5 A g−1 in 6 M KOH electrolyte and also had excellent cycling stability with 95% of capacitance after 2000 cycles, owing to the naturally heteroatoms and unique hierarchical nanopores contributed pseudo-capacitance and provided active sites for facilitating electrolyte ions diffusion. In addition, the carbon derived at 900 °C had CO2 uptake of 6.48 mmol g−1 at 20 bar and 25 °C.
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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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