Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6608052 | Electrochimica Acta | 2016 | 27 Pages |
Abstract
The re-stacking of reduced graphene oxide (rGO) is the main reason to decrease its surface area and the capacitance. A method to prevent graphene sheets from re-stacking is developed in this work by combining glucose filler with a drying process. The rGO/C composite is synthesized via a heat-dry (HD) or freeze-drying (FD) process separately and then thermal reduction under 700 °C. The rGO/C composites are characterized by XRD, SEM, TEM and FTIR. The interspace of the GO sheets increases as the glucose amount increases for the freeze-drying process and re-stacking could be reduced after thermal reduction. The capacitance is evaluated via the cyclic voltammetry method, which the rGO/C composite with freeze-drying and 1 wt% glucose addition (FD-1%) could deliver the highest capacitance 157.6 Fgâ1 at 5 mV sâ1 scanning rate. This method we developed provides a way to manipulate the interspace of GO sheet and improve the capacitive performance.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Ju-Hsiang Cheng, Yi-Hsiu Chen, Yun-Sheng Yeh, Sunny Hy, Liang-Ying Kuo, Bing-Joe Hwang,